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{"id":32191,"date":"2018-06-30T09:13:54","date_gmt":"2018-06-30T02:13:54","guid":{"rendered":"https:\/\/lop12.edu.vn\/?p=32191"},"modified":"2018-06-30T09:13:54","modified_gmt":"2018-06-30T02:13:54","slug":"chuong-7-bai-38-he-thong-hoa-ve-hidrocacbon","status":"publish","type":"post","link":"https:\/\/lop12.edu.vn\/chuong-7-bai-38-he-thong-hoa-ve-hidrocacbon\/","title":{"rendered":"Ch\u01b0\u01a1ng 7: B\u00e0i 38 : H\u1ec7 th\u1ed1ng h\u00f3a v\u1ec1 hi\u0111rocacbon"},"content":{"rendered":"

B\u00e0i 1 (trang 172 SGK H\u00f3a 11):<\/b>\u00a0<\/span>So s\u00e1nh t\u00ednh ch\u1ea5t ho\u00e1 h\u1ecdc c\u1ee7a:<\/p>\n

a. Anken v\u1edbi ankin<\/p>\n

b. Ankan v\u1edbi ankylbenzen<\/p>\n

Cho v\u00ed d\u1ee5 minh ho\u1ea1<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

* So s\u00e1nh t\u00ednh ch\u1ea5t h\u00f3a h\u1ecdc anken v\u00e0 ankin:<\/p>\n

– Gi\u1ed1ng nhau :<\/p>\n

+ C\u1ed9ng hi\u0111ro.<\/p>\n

\"Gi\u1ea3i<\/p>\n

+ C\u1ed9ng brom (dung d\u1ecbch).<\/p>\n

\"Gi\u1ea3i<\/p>\n

+ C\u1ed9ng HX theo quy t\u1eafc Mac-c\u00f4p-nhi-c\u00f4p.<\/p>\n

+ L\u00e0m m\u1ea5t m\u00e0u dung d\u1ecbch KMnO4<\/sub>.<\/p>\n

\"Gi\u1ea3i<\/p>\n

– Kh\u00e1c nhau :<\/p>\n

+ Anken : Kh\u00f4ng c\u00f3 ph\u1ea3n \u1ee9ng th\u1ebf b\u1eb1ng ion kim lo\u1ea1i.<\/p>\n

+ Ankin : Ank-1-in c\u00f3 ph\u1ea3n \u1ee9ng th\u1ebf b\u1eb1ng ion kim lo\u1ea1i.<\/p>\n

\"Gi\u1ea3i<\/p>\n

B\u00e0i 2 (trang 172 SGK H\u00f3a 11):<\/b>\u00a0<\/span>Tr\u00ecnh b\u00e0y ph\u01b0\u01a1ng ph\u00e1p ho\u00e1 h\u1ecdc<\/p>\n

a. Ph\u00e2n bi\u1ec7t c\u00e1c b\u00ecnh \u0111\u1ef1ng kh\u00ed ri\u00eang bi\u1ec7t kh\u00f4ng d\u00e1n nh\u00e3n: H2<\/sub>, O2<\/sub>, CH4<\/sub>, C2<\/sub>H4<\/sub>, C2<\/sub>H2<\/sub><\/p>\n

b. T\u00e1ch ri\u00eang kh\u00ed metan t\u1eeb h\u1ed7n h\u1ee3p v\u1edbi l\u01b0\u1ee3ng nh\u1ecf c\u00e1c ch\u1ea5t C2<\/sub>H4<\/sub>, C2<\/sub>H2<\/sub>.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

a. L\u1ea5y c\u00e1c m\u1eabu kh\u00ed nh\u1ecf t\u1eeb c\u00e1c b\u00ecnh \u0111\u1eebng kh\u00ed v\u00e0 \u0111\u00e1nh s\u1ed1 theo th\u1ee9 t\u1ef1.<\/p>\n

– Cho t\u00e0n \u0111\u00f3m qua c\u00e1c m\u1eabu kh\u00ed, m\u1eabu n\u00e0o l\u00e0m t\u00e0n \u0111\u00f3m b\u00f9ng ch\u00e1y th\u00ec \u0111\u00f3 l\u00e0 O2<\/sub>.<\/p>\n

– L\u1ea7n l\u01b0\u1ee3t d\u1eabn c\u00e1c m\u1eabu kh\u00ed c\u00f2n l\u1ea1i qua dung d\u1ecbch AgNO3<\/sub>\/NH3<\/sub>, m\u1eabu kh\u00ed n\u00e0o l\u00e0m dung d\u1ecbch xu\u1ea5t hi\u1ec7n k\u1ebft t\u1ee7a v\u00e0ng th\u00ec \u0111\u00f3 l\u00e0 C2<\/sub>H2<\/sub>.<\/p>\n

CH\u2261CH + 2AgNO3<\/sub>\u00a0+ 2NH3<\/sub>\u00a0\u2192 AgC\u2261CAg\u2193 + 2NH4<\/sub>NO3<\/sub><\/p>\n

– L\u1ea7n l\u01b0\u1ee3t d\u1eabn c\u00e1c m\u1eabu kh\u00ed c\u00f2n l\u1ea1i qua dung d\u1ecbch br\u00f4m, kh\u00ed n\u00e0o l\u00e0m nh\u1ea1t m\u00e0u dung d\u1ecbch br\u00f4m th\u00ec \u0111\u00f3 l\u00e0 C2<\/sub>H4<\/sub>.<\/p>\n

CH2<\/sub>=CH2<\/sub>\u00a0+ Br2 (n\u00e2u \u0111\u1ecf)<\/sub>\u00a0\u2192 BrCH2<\/sub>-CH2<\/sub>Br\u00a0(kh\u00f4ng m\u00e0u)<\/sub><\/p>\n

– \u0110\u1ed1t ch\u00e1y hai m\u1eabu kh\u00ed c\u00f2n l\u1ea1i, d\u1eabn s\u1ea3n ph\u1ea9m qua b\u00ecnh \u0111\u1ef1ng dung d\u1ecbch Ca(OH)2<\/sub>\u00a0d\u01b0, n\u1ebfu xu\u1ea5t hi\u1ec7n k\u1ebft t\u1ee7a tr\u1eafng th\u00ec \u0111\u00f3 l\u00e0 CH4<\/sub><\/p>\n

2H2<\/sub>\u00a0+ O2<\/sub>\u00a0\u2192 2H2<\/sub>O<\/p>\n

CH4<\/sub>\u00a0+ 2O2<\/sub>\u00a0\u2192 CO2<\/sub>\u00a0+ 2H2<\/sub>O<\/p>\n

CO2<\/sub>\u00a0+ Ca(OH)2<\/sub>\u00a0\u2192 CaCO3<\/sub>\u2193 + H2<\/sub>O<\/p>\n

– Kh\u00ed c\u00f2n l\u1ea1i l\u00e0 H2<\/sub><\/p>\n

b. Cho h\u1ed7n h\u1ee3p kh\u00ed \u0111i qua dung d\u1ecbch Br2<\/sub>\u00a0d\u01b0, C2<\/sub>H4<\/sub>\u00a0v\u00e0 C2<\/sub>H2<\/sub>\u00a0s\u1ebd t\u00e1c d\u1ee5ng h\u1ebft v\u1edbi dung d\u1ecbch Br2<\/sub>, kh\u00ed \u0111i ra l\u00e0 metan.<\/p>\n

CH2<\/sub>=CH2<\/sub>\u00a0+ Br2 (n\u00e2u \u0111\u1ecf)<\/sub>\u00a0\u2192 BrCH2<\/sub>-CH2<\/sub>Br\u00a0(kh\u00f4ng m\u00e0u)<\/sub><\/p>\n

CH\u2261CH + 2Br2 (n\u00e2u \u0111\u1ecf)<\/sub>\u00a0\u2192 Br2<\/sub>CH-CHBr2<\/sub>\u00a0(kh\u00f4ng m\u00e0u)<\/sub><\/p>\n

B\u00e0i 3 (trang 172 SGK H\u00f3a 11):<\/b><\/span>\u00a0Vi\u1ebft c\u00e1c ph\u01b0\u01a1ng tr\u00ecnh ho\u00e1 h\u1ecdc c\u1ee7a c\u00e1c ph\u1ea3n \u1ee9ng ho\u00e0n th\u00e0nh d\u00e3y chuy\u1ec3n ho\u00e1 sau:<\/p>\n

\"Gi\u1ea3i<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\"Gi\u1ea3i<\/p>\n

B\u00e0i 4 (trang 172 SGK H\u00f3a 11):<\/b><\/span>\u00a0Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh ho\u00e1 h\u1ecdc t\u1ed5ng qu\u00e1t c\u1ee7a ph\u1ea3n \u1ee9ng \u0111\u1ed1t ch\u00e1y c\u00e1c lo\u1ea1i hi\u0111rocacbon \u0111\u00e3 n\u00eau trong b\u1ea3ng 7.2. Nh\u1eadn x\u00e9t v\u1ec1 t\u1ec9 l\u1ec7 s\u1ed1 mol CO2<\/sub>\u00a0v\u00e0 s\u1ed1 mol H2<\/sub>O trong s\u1ea3n ph\u1ea9m ch\u00e1y c\u1ee7a m\u1ed7i lo\u1ea1i hi\u0111rocacbon.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\"Gi\u1ea3i<\/p>\n

B\u00e0i 5 (trang 172 SGK H\u00f3a 11):<\/b><\/span>\u00a0Khi \u0111\u1ed1t ch\u00e1y ho\u00e0n to\u00e0n hi\u0111rocacbon X (l\u00e0 ch\u1ea5t l\u1ecfng \u1edf \u0111i\u1ec1u ki\u1ec7n th\u01b0\u1eddng) thu \u0111\u01b0\u1ee3c CO2<\/sub>\u00a0v\u00e0 H2<\/sub>O c\u00f3 s\u1ed1 mol theo t\u1ec9 l\u1ec7 2:1. C\u00f4ng th\u1ee9c ph\u00e2n t\u1eed c\u1ee7a X c\u00f3 th\u1ec3 l\u00e0 c\u00f4ng th\u1ee9c n\u00e0o sau \u0111\u00e2y?<\/p>\n

A. C4<\/sub>H4<\/sub>\u00a0; \u00a0\u00a0\u00a0 B. C5<\/sub>H12<\/sub><\/p>\n

C. C6<\/sub>H6<\/sub>\u00a0; \u00a0\u00a0\u00a0D. C2<\/sub>H2<\/sub><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

– \u0110\u00e1p \u00e1n\u00a0C<\/b><\/p>\n

– Khi \u0111\u1ed1t ch\u00e1y X thu \u0111\u01b0\u1ee3c CO2<\/sub>\u00a0v\u00e0 H2<\/sub>O c\u00f3 s\u1ed1 mol theo t\u1ec9 l\u1ec7 2 : 1<\/p>\n

=> X c\u00f3 s\u1ed1 C b\u1eb1ng s\u1ed1 H<\/p>\n

M\u00e0 X l\u00e0 ch\u1ea5t l\u1ecfng \u1edf \u0111i\u1ec1u ki\u1ec7n th\u01b0\u1eddng n\u00ean X ch\u1ec9 c\u00f3 th\u1ec3 l\u00e0 C6<\/sub>H6<\/sub><\/p>\n

<\/div>\n","protected":false},"excerpt":{"rendered":"

B\u00e0i 1 (trang 172 SGK H\u00f3a 11):\u00a0So s\u00e1nh t\u00ednh ch\u1ea5t ho\u00e1 h\u1ecdc c\u1ee7a: a. Anken v\u1edbi ankin b. Ankan v\u1edbi ankylbenzen Cho v\u00ed d\u1ee5 minh ho\u1ea1 L\u1eddi gi\u1ea3i: * So s\u00e1nh t\u00ednh ch\u1ea5t h\u00f3a h\u1ecdc anken v\u00e0 ankin: – Gi\u1ed1ng nhau : + C\u1ed9ng hi\u0111ro. + C\u1ed9ng brom (dung d\u1ecbch). + C\u1ed9ng HX theo quy […]<\/p>\n","protected":false},"author":3,"featured_media":32192,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_mi_skip_tracking":false,"tdm_status":"","tdm_grid_status":""},"categories":[1322],"tags":[1510,1512],"yoast_head":"\nCh\u01b0\u01a1ng 7: B\u00e0i 38 : H\u1ec7 th\u1ed1ng h\u00f3a v\u1ec1 hi\u0111rocacbon<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/lop12.edu.vn\/chuong-7-bai-38-he-thong-hoa-ve-hidrocacbon\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Ch\u01b0\u01a1ng 7: B\u00e0i 38 : H\u1ec7 th\u1ed1ng h\u00f3a v\u1ec1 hi\u0111rocacbon\" \/>\n<meta property=\"og:description\" content=\"B\u00e0i 1 (trang 172 SGK H\u00f3a 11):\u00a0So s\u00e1nh t\u00ednh ch\u1ea5t ho\u00e1 h\u1ecdc c\u1ee7a: a. Anken v\u1edbi ankin b. 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Anken v\u1edbi ankin b. 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