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{"id":32142,"date":"2018-06-29T09:55:42","date_gmt":"2018-06-29T02:55:42","guid":{"rendered":"https:\/\/lop12.edu.vn\/?p=32142"},"modified":"2018-06-29T09:55:42","modified_gmt":"2018-06-29T02:55:42","slug":"chuong-9-bai-45-axit-cacboxylic","status":"publish","type":"post","link":"https:\/\/lop12.edu.vn\/chuong-9-bai-45-axit-cacboxylic\/","title":{"rendered":"Ch\u01b0\u01a1ng 9: B\u00e0i 45 : Axit cacboxylic"},"content":{"rendered":"

B\u00e0i 1 (trang 210 SGK H\u00f3a 11):<\/b>\u00a0<\/span>Th\u1ebf n\u00e0o l\u00e0 axit cacbonxylic? Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o, g\u1ecdi t\u00ean c\u00e1c axit c\u00f3 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed C4<\/sub>H2<\/sub>O2<\/sub>.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

– \u0110\u1ecbnh ngh\u0129a axit cacboxylic : l\u00e0 nh\u1eefng h\u1ee3p ch\u1ea5t h\u1eefu c\u01a1 m\u00e0 ph\u00e2n t\u1eed c\u00f3 nh\u00f3m cacboxyl (-COOH) li\u00ean k\u1ebft tr\u1ef1c ti\u1ebfp v\u1edbi nguy\u00ean t\u1eed cacbon(1)<\/sub>\u00a0ho\u1eb7c nguy\u00ean t\u1eed hi\u0111ro.<\/p>\n

((1): Nguy\u00ean t\u1eed cacbon n\u00e0y c\u00f3 th\u1ebb c\u1ee7a g\u1ed1c hi\u0111rocacbon ho\u1eb7c c\u1ee7a nh\u00f3m -COOH kh\u00e1c.)<\/p>\n

\"Gi\u1ea3i<\/p>\n

B\u00e0i 2 (trang 210 SGK H\u00f3a 11):<\/b>\u00a0<\/span>T\u1eeb c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o, h\u00e3y gi\u1ea3i th\u00edch t\u1ea1i sao axit fomic c\u00f3 t\u00ednh ch\u1ea5t c\u1ee7a m\u1ed9t an\u0111ehit.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\"Gi\u1ea3i<\/p>\n

\n

B\u00e0i 3 (trang 210 SGK H\u00f3a 11):<\/b><\/span>\u00a0T\u1eeb metan v\u00e0 c\u00e1c ch\u1ea5t v\u00f4 c\u01a1 c\u1ea7n thi\u1ebft kh\u00e1c c\u00f3 th\u1ec3 \u0111i\u1ec1u ch\u1ebf \u0111\u01b0\u1ee3c axit fomic, axit axetic. Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc c\u1ee7a c\u00e1c ph\u1ea3n \u1ee9ng x\u1ea3y ra.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\"Gi\u1ea3iB\u00e0i 4 (trang 210 SGK H\u00f3a 11):<\/b><\/span>\u00a0Ch\u1ea5t Y c\u00f3 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed C4<\/sub>H8<\/sub>O2<\/sub>\u00a0t\u00e1c d\u1ee5ng v\u1edbi NaOH t\u1ea1o th\u00e0nh ch\u1ea5t Z (C4<\/sub>H7<\/sub>O2<\/sub>Na). V\u1eady Y thu\u1ed9c lo\u1ea1i h\u1ee3p ch\u1ea5t n\u00e0o sau \u0111\u00e2y?<\/p>\n

A. An\u0111ehit ; \u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0 B. Axit.<\/p>\n

C. Ancol ; \u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0D. Xeton.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

– \u0110\u00e1p \u00e1n B.<\/p>\n

– Ph\u01b0\u01a1ng tr\u00ecnh minh h\u1ecda:<\/p>\n

CH3<\/sub>CH2<\/sub>CH2<\/sub>COOH + NaOH \u2192 CH3<\/sub>CH2<\/sub>CH2<\/sub>COONa + H2<\/sub>O<\/p>\n

\n
\n
\u00a0<\/span>B\u00e0i 5 (trang 210 SGK H\u00f3a 11):<\/b>\u00a0<\/span>\u0110\u1ec3 trung h\u00f2a 150,0 gam dung d\u1ecbch 7,40% c\u1ee7a axit no, m\u1ea1ch h\u1edf, \u0111\u01a1n ch\u1ee9c X c\u1ea7n d\u00f9ng 100,0 ml dung d\u1ecbch NaOH 1,50M. Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o v\u00e0 g\u1ecdi t\u00ean c\u1ee7a ch\u1ea5t X.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

G\u1ecdi c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed c\u1ee7a X l\u00e0 Cn<\/sub>H2n+1<\/sub>COOH (n \u2265 1)<\/p>\n

Ta c\u00f3:<\/p>\n

\"Gi\u1ea3i\u00a0\u00a0\u00a0 \u00a0\u00a0\u00a0mNaOH<\/sub>\u00a0= 0,1.1,5 = 0,15(mol)<\/p>\n

Ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng:<\/p>\n

Cn<\/sub>H2n+1<\/sub>COOH + NaOH \u2192 Cn<\/sub>H2n+1<\/sub>COONa + H2<\/sub>O<\/p>\n

Theo ph\u01b0\u01a1ng tr\u00ecnh: nCnH2n+1COOH<\/sub>\u00a0= nNaOH<\/sub>\u00a0= 0,15 (mol)<\/p>\n

\"Gi\u1ea3i<\/div>\n

\n

B\u00e0i 6 (trang 210 SGK H\u00f3a 11):<\/b>\u00a0<\/span>Trung h\u00f2a 16,60gam h\u1ed7n h\u1ee3p g\u1ed3m axit axetic v\u00e0 axit fomic b\u1eb1ng dung d\u1ecbch natri hi\u0111roxit thu \u0111\u01b0\u1ee3c 23,20 gam h\u1ed7n h\u1ee3p hai mu\u1ed1i.<\/p>\n

a. Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc c\u1ee7a c\u00e1c ph\u1ea3n \u1ee9ng \u1edf d\u1ea1ng ph\u00e2n t\u1eed v\u00e0 ion r\u00fat g\u1ecdn.<\/p>\n

b. X\u00e1c \u0111\u1ecbnh th\u00e0nh ph\u1ea7n ph\u1ea7n tr\u0103m kh\u1ed1i l\u01b0\u1ee3ng c\u1ee7a m\u1ed7i ch\u1ea5t trong h\u1ed7n h\u1ee3p tr\u01b0\u1edbc v\u00e0 sau ph\u1ea3n \u1ee9ng.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

a) G\u1ecdi s\u1ed1 mol c\u1ee7a axit axetic v\u00e0 axit fomic l\u1ea7n l\u01b0\u1ee3t l\u00e0 x v\u00e0 y (mol)<\/p>\n

Ph\u01b0\u01a1ng tr\u00ecnh ho\u00e1 h\u1ecdc \u1edf d\u1ea1ng ph\u00e2n t\u1eed:<\/p>\n

\"Gi\u1ea3iPh\u01b0\u01a1ng tr\u00ecnh ho\u00e1 h\u1ecdc \u1edf d\u1ea1ng ion:<\/p>\n

CH3<\/sub>COOH + OH–<\/sup>\u00a0\u2192 CH3<\/sub>COO–<\/sup>\u00a0+ H2<\/sub>O<\/p>\n

HCOOH + OH–<\/sup>\u00a0\u2192 HCOO–<\/sup>\u00a0+ H2<\/sub>O<\/p>\n

b) Theo \u0111\u1ec1 b\u00e0i ta c\u00f3 h\u1ec7 ph\u01b0\u01a1ng tr\u00ecnh:<\/p>\n

\"Gi\u1ea3i<\/div>\n

\n

B\u00e0i 7 (trang 210 SGK H\u00f3a 11):<\/b><\/span>\u00a0\u0110un 12,0 gam axit axetic v\u1edbi m\u1ed9t l\u01b0\u1ee3ng d\u01b0 ancol etylic ( c\u00f3 axit H2<\/sub>SO4<\/sub>\u00a0\u0111\u1eb7c l\u00e0m x\u00fac t\u00e1c ). \u0110\u1ebfn khi d\u1eebng th\u00ed nghi\u1ec7m thu \u0111\u01b0\u1ee3c 12,3 gam este.<\/p>\n

a. Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc c\u1ee7a ph\u1ea3n \u1ee9ng.<\/p>\n

b. T\u00ednh ph\u1ea7n tr\u0103m kh\u1ed1i l\u01b0\u1ee3ng c\u1ee7a axit \u0111\u00e3 tham gia ph\u1ea3n \u1ee9ng este h\u00f3a.<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

a) Ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc:<\/p>\n

CH3<\/sub>COOH + C2<\/sub>H5<\/sub>OH —H2<\/sub>SO4<\/sub><\/sup>\u2192 CH3<\/sub>COOC2<\/sub>H5<\/sub>\u00a0+ H2<\/sub>O<\/p>\n

b)<\/p>\n

\"Gi\u1ea3i<\/p>\n

<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

B\u00e0i 1 (trang 210 SGK H\u00f3a 11):\u00a0Th\u1ebf n\u00e0o l\u00e0 axit cacbonxylic? Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o, g\u1ecdi t\u00ean c\u00e1c axit c\u00f3 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed C4H2O2. L\u1eddi gi\u1ea3i: – \u0110\u1ecbnh ngh\u0129a axit cacboxylic : l\u00e0 nh\u1eefng h\u1ee3p ch\u1ea5t h\u1eefu c\u01a1 m\u00e0 ph\u00e2n t\u1eed c\u00f3 nh\u00f3m cacboxyl (-COOH) li\u00ean k\u1ebft tr\u1ef1c ti\u1ebfp v\u1edbi nguy\u00ean t\u1eed cacbon(1)\u00a0ho\u1eb7c […]<\/p>\n","protected":false},"author":3,"featured_media":32143,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_mi_skip_tracking":false,"tdm_status":"","tdm_grid_status":""},"categories":[1322],"tags":[1513,1512],"yoast_head":"\nCh\u01b0\u01a1ng 9: B\u00e0i 45 : Axit cacboxylic<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/lop12.edu.vn\/chuong-9-bai-45-axit-cacboxylic\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Ch\u01b0\u01a1ng 9: B\u00e0i 45 : Axit cacboxylic\" \/>\n<meta property=\"og:description\" content=\"B\u00e0i 1 (trang 210 SGK H\u00f3a 11):\u00a0Th\u1ebf n\u00e0o l\u00e0 axit cacbonxylic? Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o, g\u1ecdi t\u00ean c\u00e1c axit c\u00f3 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed C4H2O2. 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