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{"id":25490,"date":"2018-04-06T15:49:26","date_gmt":"2018-04-06T08:49:26","guid":{"rendered":"https:\/\/lop12.edu.vn\/?p=25490"},"modified":"2018-04-06T15:49:26","modified_gmt":"2018-04-06T08:49:26","slug":"chuong-1-bai-4-luyen-tap-moi-lien-he-giua-hidrocacbon-va-mot-so-dan-xuat-cua-hidrocacbon-2","status":"publish","type":"post","link":"https:\/\/lop12.edu.vn\/chuong-1-bai-4-luyen-tap-moi-lien-he-giua-hidrocacbon-va-mot-so-dan-xuat-cua-hidrocacbon-2\/","title":{"rendered":"Ch\u01b0\u01a1ng 1 – B\u00e0i 4: Luy\u1ec7n t\u1eadp: M\u1ed1i li\u00ean h\u1ec7 gi\u1eefa hi\u0111rocacbon v\u00e0 m\u1ed9t s\u1ed1 d\u1eabn xu\u1ea5t c\u1ee7a hi\u0111rocacbon"},"content":{"rendered":"

B\u00e0i 1 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Nguy\u00ean li\u1ec7u cho c\u00f4ng nghi\u1ec7p h\u00f3a ch\u1ea5t h\u1eefu c\u01a1 ng\u00e0y nay d\u1ef1a ch\u1ee7 y\u1ebfu v\u00e0o :<\/strong><\/p>\n

A. kh\u00ed thi\u00ean nhi\u00ean<\/p>\n

B. than \u0111\u00e1 v\u00e0 \u0111\u00e1 v\u00f4i<\/p>\n

C. th\u1ef1c v\u1eadt<\/p>\n

D. d\u1ea7u m\u1ecf<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\u0110\u00e1p \u00e1n D<\/p>\n

B\u00e0i 2 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0a. V\u00ec sao trong s\u01a1 \u0111\u1ed3 m\u1ed1i li\u00ean h\u1ec7 gi\u1eefa hidrocacbon v\u00e0 d\u1eabn xu\u1ea5t ch\u1ee9a oxi, ankan l\u1ea1i \u0111\u01b0\u1ee3c \u0111\u1eb7t \u1edf trung t\u00e2m ?<\/strong><\/p>\n

b. Xu\u1ea5t ph\u00e1t t\u1eeb \u00f4 trung t\u00e2m l\u1ea7n l\u01b0\u1ee3t \u0111i\u1ec1n v\u00e0o \u0111\u00f3 metan, etan v\u00e0 n-hexan r\u1ed3i vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng (n\u1ebfu c\u00f3) theo c\u00e1c m\u0169i t\u00ean \u0111\u00e3 ch\u1ec9 \u0111\u1ec3 \u0111i \u0111\u1ebfn c\u00e1c \u00f4 kh\u00e1c trong s\u01a1 \u0111\u1ed3( \u201cd\u1ea1o quanh s\u01a1 \u0111\u1ed3\u201d)<\/p>\n

c. H\u00e3y th\u1eed t\u00ecm m\u1ed9t hidrocacbon no \u0111\u1ec3 t\u1eeb \u0111\u00f3 \u0111i theo h\u1ebft m\u1ecdi m\u0169i t\u00ean \u0111\u1ebfn h\u1ebft m\u1ecdi \u00f4 c\u1ee7a s\u01a1 \u0111\u1ed3<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

a. Ankan \u0111\u01b0\u1ee3c \u0111\u1eb7t \u1edf trung t\u00e2m c\u1ee7a s\u01a1 \u0111\u1ed3 do ankan l\u00e0 nguy\u00ean li\u1ec7u ch\u00ednh \u0111\u1ec3 t\u1ed5ng h\u1ee3p ra c\u00e1c hidrocacbon kh\u00e1c v\u00e0 d\u1eabn xu\u1ea5t c\u00f3 oxi c\u1ee7a ch\u00fang<\/p>\n

b. S\u01a1 \u0111\u1ed3 c\u1ee7a metan<\/p>\n

S\u01a1 \u0111\u1ed3 v\u00e0 ph\u1ea3n \u1ee9ng c\u1ee7a metan<\/p>\n

\"\"<\/p>\n

S\u01a1 \u0111\u1ed3 v\u00e0 ph\u1ea3n \u1ee9ng c\u1ee7a etan<\/p>\n

\"\"<\/p>\n

B\u00e0i 3 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0H\u00e3y d\u00f9ng s\u01a1 \u0111\u1ed3 ph\u1ea3n \u1ee9ng ch\u1ee9ng t\u1ecf r\u1eb1ng t\u1eeb metan c\u00f3 th\u1ec3 t\u1ed5ng h\u1ee3p \u0111\u01b0\u1ee3c c\u00e1c ancol, andehit v\u00e0 axit c\u00f3 t\u1eeb 1 \u0111\u1ebfn 2 nguy\u00ean t\u1eed C trong ph\u00e2n t\u1eed<\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

T\u1eeb metan t\u1ed5ng h\u1ee3p c\u00e1c ancol, andehit v\u00e0 axit c\u00f3 t\u1eeb 1 \u0111\u1ebfn 2 nguy\u00ean t\u1eed C trong ph\u00e2n t\u1eed<\/p>\n

\"\"<\/p>\n

B\u00e0i 4 (trang 23 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0H\u00e3y vi\u1ebft s\u01a1 \u0111\u1ed3 ph\u1ea3n \u1ee9ng t\u1eeb etilen v\u00e0 toluen \u0111i\u1ec1u ch\u1ebf ra c\u00e1c h\u1ee3p ch\u1ea5t sau<\/strong><\/p>\n

a) Etyl benzoat<\/p>\n

b) 1-Etyl-4-metylbenzen<\/p>\n

c) Benzyl axetat<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

T\u1eeb etilen v\u00e0 toluen vi\u1ebft s\u01a1 \u0111\u1ed3 \u0111i\u1ec1u ch\u1ebf ra<\/p>\n

a) etyl benzoat: C6<\/sub>H5<\/sub>COOC2<\/sub>H5<\/sub><\/p>\n

\"\"<\/p>\n

B\u00e0i 5 (trang 23 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0H\u00e3y vi\u1ebft s\u01a1 \u0111\u1ed3 ph\u1ea3n \u1ee9ng t\u1eeb etilen v\u00e0 toluen \u0111i\u1ec1u ch\u1ebf ra c\u00e1c h\u1ee3p ch\u1ea5t sau:<\/strong><\/p>\n

\"\"<\/p>\n

a. Ch\u00fang thu\u1ed9c ch\u1ee9c h\u1eefu c\u01a1 n\u00e0o?<\/p>\n

b. H\u00e3y vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o thu g\u1ecdn v\u00e0 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed c\u1ee7a ch\u00fang<\/p>\n

c. G\u1ecdi t\u00ean hai h\u1ee3p ch\u1ea5t \u0111\u1ea7u theo danh ph\u00e1p IUPAC<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

C\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o thu g\u1ecdn nh\u1ea5t<\/p>\n

a. Xitronelal v\u00e0 geranial thu\u1ed9c ch\u1ee9c andehit do ph\u00e2n t\u1eed c\u00f3 ch\u1ee9a nh\u00f3m ch\u1ee9c \u2013CH=O. Metol thu\u1ed9c ch\u1ee9c r\u01b0\u1ee3u (ancol) v\u00ec ph\u00e2n t\u1eed c\u00f3 ch\u1ee9a nh\u00f3m \u2013OH<\/p>\n

\"\"<\/p>\n

c. T\u00ean c\u1ee7a xitronelal v\u00e0 geranial theo IUPAC<\/p>\n

Xitronelal : 3,7-dimetyl oct-6-en-1-al<\/p>\n

Geranial : 3,7-dimetyl oct-2,6-dien-1-al<\/p>\n

B\u00e0i 6 (trang 23 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0H\u00e3y ho\u00e0n th\u00e0nh c\u00e1c s\u01a1 \u0111\u1ed3 ph\u1ea3n \u1ee9ng sau :<\/strong><\/p>\n

\"\"<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\u00a0a. C\u00e1c ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng<\/div>\n

\"\"<\/p>\n

B\u00e0i 7 (trang 23 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0\u0110un n\u00f3ng 3,21 gam h\u1ed7n h\u1ee3p A g\u1ed3m hai ch\u1ea5t h\u1eefu c\u01a1 B v\u00e0 C c\u00f3 c\u00f9ng nh\u00f3m ch\u1ee9c v\u1edbi dung d\u1ecbch NaOH d\u01b0 thu \u0111\u01b0\u1ee3c h\u1ed7n h\u1ee3p mu\u1ed1i natri c\u1ee7a hai axit no \u0111\u01a1n ch\u1ee9c k\u1ebf ti\u1ebfp nhau trong d\u00e3y \u0111\u1ed3ng \u0111\u1eb3ng v\u00e0 m\u1ed9t ch\u1ea5t l\u1ecfng D. Ch\u1ea5t D ph\u1ea3n \u1ee9ng v\u1edbi CuO \u0111un n\u00f3ng cho s\u1ea3n ph\u1ea9m c\u00f3 ph\u1ea3n \u1ee9ng tr\u00e1ng g\u01b0\u01a1ng. Cho 1\/10 l\u01b0\u1ee3ng ch\u1ea5t D ph\u1ea3n \u1ee9ng v\u1edbi natri \u0111\u01b0\u1ee3c 33,6 ml H2<\/sub>\u00a0(\u0111ktc). T\u1ec9 kh\u1ed1i h\u01a1i c\u1ee7a D so v\u1edbi kh\u00f4ng kh\u00ed l\u00e0 2<\/strong><\/p>\n

a. x\u00e1c \u0111\u1ecbnh c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o c\u1ee7a B, C v\u00e0 D<\/p>\n

b. T\u00ednh th\u00e0nh ph\u1ea7n % kh\u1ed1i l\u01b0\u1ee3ng h\u1ed7n h\u1ee3p A<\/p>\n

c. Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng c\u1ee7a B ho\u1eb7c C v\u1edbi H2<\/sub>\u00a0(Ni, to<\/sup>) , Br2<\/sub>\u00a0v\u00e0 ph\u1ea3n \u1ee9ng t\u1ea1o th\u00e0nh polime c\u1ee7a ch\u00fang<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

Hai ch\u1ea5t h\u1eefu c\u01a1 c\u00f9ng ch\u1ee9c t\u00e1c d\u1ee5ng v\u1edbi NaOH d\u01b0 t\u1ea1o ra 2 mu\u1ed1i natri c\u1ee7a 2 axit no \u0111\u01a1n ch\u1ee9c k\u1ebf ti\u1ebfp v\u00e0 m\u1ed9t ch\u1ea5t l\u1ecfng D. D + CuO \u2192(to<\/sup>) s\u1ea3n ph\u1ea9m c\u00f3 tr\u00e1ng b\u1ea1c.<\/p>\n

Do \u0111\u00f3 D l\u00e0 ancol b\u1eadc 1 : R \u2013 CH2<\/sub>OH<\/p>\n

B v\u00e0 C l\u00e0 2 este t\u1ea1o b\u1edfi 2 axit no, \u0111\u01a1n ch\u1ee9c k\u1ebf ti\u1ebfp nhau c\u00f3 c\u00f4ng th\u1ee9c chung l\u00e0 Cn<\/sub>H2n+1<\/sub>COOH v\u00e0 ancol D.<\/p>\n

– T\u00ecm ancol D : dd\/kk = 2 \u2192 MD<\/sub>\u00a0= 29.2 = 58<\/p>\n

R\u2019 + 14 + 17 = 58 \u2192 R\u2019 = 27 (C2<\/sub>H3<\/sub>)<\/p>\n

D l\u00e0 C3<\/sub>H5<\/sub>OH : CH2<\/sub>=CH-CH2<\/sub>OH (ancol anlylic)<\/p>\n

– T\u00ecm B, C : \u0110\u1eb7t c\u00f4ng th\u1ee9c chung cho B v\u00e0 C l\u00e0 Cn<\/sub>H2n+1<\/sub>COOC3<\/sub>H5<\/sub><\/p>\n

C\u00e1c ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng :<\/p>\n

Cn<\/sub>H2n+1<\/sub>COOC3<\/sub>H5<\/sub>\u00a0+ NaOH \u2192 CnH2<\/sub>n+1COONa + C3<\/sub>H5<\/sub>OH (1)<\/p>\n

C3<\/sub>H5<\/sub>OH + Na \u2192 C3<\/sub>H5<\/sub>ONa + 1\/2 H2<\/sub>(bay h\u01a1i) (2)<\/p>\n

S\u1ed1 mol H2<\/sub>\u00a0= 0,0366 : 22,4 = 0,0015<\/p>\n

V\u1eady 1:10 s\u1ed1 mol D l\u00e0 nC3<\/sub>H5<\/sub>OH = 2.0,0015 = 0,003 mol<\/p>\n

Theo (1) s\u1ed1 mol este Cn<\/sub>H2n+1<\/sub>COOC3<\/sub>H5<\/sub>\u00a0b\u1eb1ng s\u1ed1 mol ancol trong c\u1ea3 l\u01b0\u1ee3ng D:<\/p>\n

neste<\/sub>\u00a0= 10*0,003 = 0,03 mol<\/p>\n

\"\"<\/p>\n

%(m)CH3<\/sub>COOC3<\/sub>H5<\/sub>\u00a0= (0,015.100: 3,21).100% = 46,73 %<\/p>\n

%(m) C2<\/sub>H5<\/sub>COOC3<\/sub>H5<\/sub>\u00a0= 53,27%<\/p>\n

c. Ph\u01b0\u01a1ng tr\u00ecnh ph\u1ea3n \u1ee9ng c\u1ee7a m\u1ed9t este v\u1edbi H2<\/sub>, Br2<\/sub>\u00a0v\u00e0 t\u1ea1o polime<\/p>\n

\"\"<\/p>\n

B\u00e0i 8 (trang 23 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0H\u00e3y ph\u00e2n t\u00edch c\u00e1c ch\u1ea5t v\u00e0o c\u00e1c lo\u1ea1i sau (m\u1ed9t ch\u1ea5t c\u00f3 th\u1ec3 thu\u1ed9c nhi\u1ec1u lo\u1ea1i<\/strong><\/p>\n

\"\"<\/p>\n

L\u1eddi gi\u1ea3i<\/strong><\/p>\n

A. Ch\u1ea5t b\u00e9o : e<\/p>\n

B. Ch\u1ea5t gi\u1eb7t r\u1eeda : b,c<\/p>\n

C. Este : a, d, e<\/p>\n

D. Lipit : e<\/p>\n

B\u00e0i 9 (trang 24 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Ch\u1ec9 s\u1ed1 x\u00e0 ph\u00f2ng h\u00f3a c\u1ee7a ch\u1ea5t b\u00e9o l\u00e0 s\u1ed1 mg KOH c\u1ea7n \u0111\u1ec3 x\u00e0 ph\u00f2ng h\u00f3a triglixerit v\u00e0 trung h\u00f2a axit b\u00e9o t\u1ef1 do trong m\u1ed9t gam ch\u1ea5t b\u00e9o (t\u1ee9c x\u00e0 ph\u00f2ng h\u00f3a ho\u00e0n to\u00e0n 1 gam ch\u1ea5t b\u00e9o).H\u00e3y t\u00ednh ch\u1ec9 s\u1ed1 x\u00e0 ph\u00f2ng h\u00f3a c\u1ee7a m\u1ed9t ch\u1ea5t b\u00e9o, bi\u1ebft r\u1eb1ng khi x\u00e0 ph\u00f2ng h\u00f3a ho\u00e0n to\u00e0n 1,5 gam ch\u1ea5t b\u00e9o \u0111\u00f3 c\u1ea7n 50 ml dung d\u1ecbch KOH 0,1 M<\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

nKOH<\/sub>\u00a0= 0,05.0,1 = 0,005 (mol)<\/p>\n

=> mKOH<\/sub>\u00a0= 0,005. 56 = 0,28 g = 280 (mg)<\/p>\n

X\u00e0 ph\u00f2ng h\u00f3a 1,5 gam ch\u1ea5t b\u00e9o c\u1ea7n 280 mg KOH do \u0111\u00f3 x\u00e0 ph\u00f2ng h\u00f3a 1 gam ch\u1ea5t b\u00e9o c\u1ea7n 186,7 mg KOH. V\u1eady ch\u1ec9 s\u1ed1 x\u00e0 ph\u00f2ng l\u00e0 186,7.<\/p>\n","protected":false},"excerpt":{"rendered":"

B\u00e0i 1 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Nguy\u00ean li\u1ec7u cho c\u00f4ng nghi\u1ec7p h\u00f3a ch\u1ea5t h\u1eefu c\u01a1 ng\u00e0y nay d\u1ef1a ch\u1ee7 y\u1ebfu v\u00e0o : A. kh\u00ed thi\u00ean nhi\u00ean B. than \u0111\u00e1 v\u00e0 \u0111\u00e1 v\u00f4i C. th\u1ef1c v\u1eadt D. d\u1ea7u m\u1ecf L\u1eddi gi\u1ea3i: \u0110\u00e1p \u00e1n D B\u00e0i 2 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0a. V\u00ec […]<\/p>\n","protected":false},"author":3,"featured_media":25493,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_mi_skip_tracking":false,"tdm_status":"","tdm_grid_status":""},"categories":[1306],"tags":[1436,1435],"yoast_head":"\nCh\u01b0\u01a1ng 1 - B\u00e0i 4: Luy\u1ec7n t\u1eadp: M\u1ed1i li\u00ean h\u1ec7 gi\u1eefa hi\u0111rocacbon v\u00e0 m\u1ed9t s\u1ed1 d\u1eabn xu\u1ea5t c\u1ee7a hi\u0111rocacbon<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/lop12.edu.vn\/chuong-1-bai-4-luyen-tap-moi-lien-he-giua-hidrocacbon-va-mot-so-dan-xuat-cua-hidrocacbon-2\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Ch\u01b0\u01a1ng 1 - B\u00e0i 4: Luy\u1ec7n t\u1eadp: M\u1ed1i li\u00ean h\u1ec7 gi\u1eefa hi\u0111rocacbon v\u00e0 m\u1ed9t s\u1ed1 d\u1eabn xu\u1ea5t c\u1ee7a hi\u0111rocacbon\" \/>\n<meta property=\"og:description\" content=\"B\u00e0i 1 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Nguy\u00ean li\u1ec7u cho c\u00f4ng nghi\u1ec7p h\u00f3a ch\u1ea5t h\u1eefu c\u01a1 ng\u00e0y nay d\u1ef1a ch\u1ee7 y\u1ebfu v\u00e0o : A. kh\u00ed thi\u00ean nhi\u00ean B. than \u0111\u00e1 v\u00e0 \u0111\u00e1 v\u00f4i C. th\u1ef1c v\u1eadt D. d\u1ea7u m\u1ecf L\u1eddi gi\u1ea3i: \u0110\u00e1p \u00e1n D B\u00e0i 2 (trang 22 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0a. 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