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{"id":25414,"date":"2018-04-05T22:22:19","date_gmt":"2018-04-05T15:22:19","guid":{"rendered":"https:\/\/lop12.edu.vn\/?p=25414"},"modified":"2018-04-05T22:22:19","modified_gmt":"2018-04-05T15:22:19","slug":"chuong-3-bai-12-amino-axit-3","status":"publish","type":"post","link":"https:\/\/lop12.edu.vn\/chuong-3-bai-12-amino-axit-3\/","title":{"rendered":"Ch\u01b0\u01a1ng 3 – B\u00e0i 12: Amino axit"},"content":{"rendered":"

B\u00e0i 1 (trang 66 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Ph\u00e1t bi\u1ec3u n\u00e0o sau \u0111\u00e2y \u0111\u00fang ?<\/strong><\/p>\n

A. Trong ph\u00e2n t\u1eed amino axit ch\u1ec9 c\u00f3 m\u1ed9t nh\u00f3m \u2013NH2<\/sub>\u00a0v\u00e0 m\u1ed9t nh\u00f3m \u2013COOH<\/p>\n

B. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u kh\u00f4ng l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm<\/p>\n

C. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm<\/p>\n

D. C\u00e1c amino axit \u0111\u1ec1u l\u00e0 ch\u1ea5t r\u1eafn \u1edf nhi\u1ec7t \u0111\u1ed9 th\u01b0\u1eddng<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\u0110\u00e1p \u00e1n D<\/p>\n

\n
\n

B\u00e0i 2 (trang 66 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0pH c\u1ee7a dung d\u1ecbch 3 ch\u1ea5t NH2<\/sub>CH2<\/sub>COOH, CH3<\/sub>CH2<\/sub>COOH, CH3<\/sub>[CH2<\/sub>]3<\/sub>NH2<\/sub>\u00a0t\u0103ng theo tr\u1eadt t\u1ef1 n\u00e0o sau \u0111\u00e2y?<\/strong><\/p>\n

A. CH3<\/sub>[CH2<\/sub>]3<\/sub>NH2<\/sub>\u00a0< NH2<\/sub>CH2<\/sub>COOH < CH3<\/sub>CH2<\/sub>COOH<\/p>\n

B. CH3<\/sub>CH2<\/sub>COOH < NH2<\/sub>CH2<\/sub>COOH < CH3<\/sub>[CH2<\/sub>]3<\/sub>NH2<\/sub><\/p>\n

C. NH2<\/sub>CH2<\/sub>COOH < CH3<\/sub>CH2<\/sub>COOH < CH3<\/sub>[CH2<\/sub>]3<\/sub>NH2<\/sub><\/p>\n

D. CH3<\/sub>CH2<\/sub>COOH < CH3<\/sub>[CH2<\/sub>]3<\/sub>NH2<\/sub>\u00a0< NH2<\/sub>CH2<\/sub>COOH<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\u0110\u00e1p \u00e1n B<\/p>\n

B\u00e0i 3 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Amin axit l\u00e0 g\u00ec? Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o v\u00e0 g\u1ecdi t\u00ean c\u00e1c amino axit c\u00f3 c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed l\u00e0 C4<\/sub>H9<\/sub>NO2<\/sub><\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

Amino axit l\u00e0 lo\u1ea1i h\u1ee3p ch\u1ea5t h\u1eefu c\u01a1 t\u1ea1p ch\u1ee9c m\u00e0 ph\u00e2n t\u1eed ch\u1ee9a \u0111\u1ed3ng th\u1eddi nh\u00f3m amino (-NH2<\/sub>) v\u00e0 nh\u00f3m cacboxyl(-COOH)<\/p>\n

C\u00e1c amino axit c\u00f3 CTPT C4<\/sub>H9<\/sub>NO2<\/sub><\/p>\n

\"\"<\/p>\n

B\u00e0i 4 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Vi\u1ebft c\u00e1c ph\u01b0\u01a1ng tr\u00ecnh c\u1ee7a ph\u1ea3n \u1ee9ng gi\u1eefa axit 2-amino propanoic v\u1edbi c\u00e1c ch\u1ea5t sau : NaOH, H2<\/sub>SO4<\/sub>, CH3<\/sub>OH c\u00f3 m\u1eb7t kh\u00ed HCl b\u00e3o h\u00f2a, HNO2<\/sub><\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

C\u00e1c ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc c\u1ee7a axit 2-aminopropanoic (alanin)<\/p>\n

\"\"<\/p>\n

B\u00e0i 5 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Vi\u1ebft ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc bi\u1ec3u di\u1ec5n ph\u1ea3n \u1ee9ng tr\u00f9ng ng\u01b0ng c\u1ee7a amino axit sau :<\/strong><\/p>\n

a. Axit 7-amino heptanoic<\/strong><\/p>\n

b. Axit 2-amino propanoic<\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

Ph\u01b0\u01a1ng tr\u00ecnh tr\u00f9ng ng\u01b0ng<\/p>\n

a. Axit 7-amino heptanoic H2<\/sub>N-(CH2<\/sub>)6<\/sub>-COOH<\/p>\n

\"\"<\/p>\n

b. Axit 2-amino propanoic CH3<\/sub>-CH(NH2<\/sub>)COOH<\/p>\n

\"\"<\/p>\n

B\u00e0i 6 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o c\u1ee7a c\u00e1c amino axit sau \u0111\u00e2y:<\/strong><\/p>\n

a. Axit 2-amino-3-phenyl propanoic (phenyl alanin)<\/p>\n

b. Axit 2-amino-3-metyl butanoic (valin)<\/p>\n

c. Axit 2-amino-4-metyl pentanoic(leuxin)<\/p>\n

d. Axit 2-amino-3-metyl pentanoic (iisoleuxin )<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

\"\"<\/p>\n

B\u00e0i 7 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Cho s\u01a1 \u0111\u1ed3 chuy\u1ec3n h\u00f3a sau :<\/strong><\/p>\n

\"\"<\/p>\n

H\u00e3y vi\u1ebft c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o c\u1ee7a X, Y, Z v\u00e0 vi\u1ebft c\u00e1c ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc c\u1ee7a c\u00e1c ph\u1ea3n \u1ee9ng x\u1ea3y ra?<\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

C\u00e1c ph\u01b0\u01a1ng tr\u00ecnh h\u00f3a h\u1ecdc bi\u1ec3u di\u1ec5n theo s\u01a1 \u0111\u1ed3 chuy\u1ec3n h\u00f3a :<\/p>\n

\"\"<\/p>\n

B\u00e0i 8 (trang 67 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Cho 0,1 mol h\u1ee3p ch\u1ea5t A t\u00e1c d\u1ee5ng v\u1eeba \u0111\u1ee7 v\u1edbi 80ml dung d\u1ecbch HCl 1,25M, sau \u0111\u00f3 c\u00f4 c\u1ea1n dung d\u1ecbch th\u00ec \u0111\u01b0\u1ee3c 18,75 g mu\u1ed1i. M\u1eb7t kh\u00e1c, n\u1ebfu cho 0,1 mol A t\u00e1c d\u1ee5ng v\u1edbi l\u01b0\u1ee3ng NaOH v\u1eeba \u0111\u1ee7, r\u1ed3i \u0111em c\u00f4 c\u1ea1n th\u00ec \u0111\u01b0\u1ee3c 17,3 gam mu\u1ed1i. X\u00e1c \u0111\u1ecbnh c\u00f4ng th\u1ee9c ph\u00e2n t\u1eed v\u00e0 c\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o c\u1ee7a A, bi\u1ebft r\u1eb1ng A l\u00e0 m\u1ed9t \u03b1-amino axit, kh\u00f4ng l\u00e0m m\u1ea5t m\u00e0u dung d\u1ecbch KMnO4<\/sub>.<\/strong><\/p>\n

L\u1eddi gi\u1ea3i:<\/b><\/p>\n

nHCl<\/sub>\u00a0= 0,08.1,25 = 0,1 mol = nA<\/p>\n

A + HCl t\u1ec9 l\u1ec7 1 : 1 \u2192 A c\u00f3 1 nh\u00f3m \u2013NH2<\/sub><\/p>\n

C\u00f4ng th\u1ee9c A c\u00f3 d\u1ea1ng : R(NH2<\/sub>)(COOH)a<\/sub><\/p>\n

(HOOC)a<\/sub>\u00a0\u2013R-NH2<\/sub>\u00a0+ HCl \u2192 (HOOC)a<\/sub>\u00a0\u2013R-NH3<\/sub>Cl<\/p>\n

H2<\/sub>N-R-(COOH)a<\/sub>\u00a0+ aNaOH \u2192 H2<\/sub>N-R-(COONa)a<\/sub>\u00a0+ aH2<\/sub>O<\/p>\n

0,1(16 + R + 67a) = 17,3 => R + 67a = 157<\/p>\n

=> a = 1; R = 90<\/p>\n

A l\u00e0 m\u1ed9t \u03b1-amino axit v\u00e0 kh\u00f4ng l\u00e0m m\u1ea5t m\u00e0u dung d\u1ecbch KMnO4<\/sub>, suy ra A c\u00f3 g\u1ed1c hidrocacbon th\u01a1m. C\u00f4ng th\u1ee9c c\u1ea5u t\u1ea1o c\u1ee7a A l\u00e0 :<\/p>\n

\"\"<\/p>\n

 <\/p>\n

 <\/p>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

B\u00e0i 1 (trang 66 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Ph\u00e1t bi\u1ec3u n\u00e0o sau \u0111\u00e2y \u0111\u00fang ? A. Trong ph\u00e2n t\u1eed amino axit ch\u1ec9 c\u00f3 m\u1ed9t nh\u00f3m \u2013NH2\u00a0v\u00e0 m\u1ed9t nh\u00f3m \u2013COOH B. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u kh\u00f4ng l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm C. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm D. […]<\/p>\n","protected":false},"author":3,"featured_media":25415,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_mi_skip_tracking":false,"tdm_status":"","tdm_grid_status":""},"categories":[1306],"tags":[1436,1435],"yoast_head":"\nCh\u01b0\u01a1ng 3 - B\u00e0i 12: Amino axit<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/lop12.edu.vn\/chuong-3-bai-12-amino-axit-3\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Ch\u01b0\u01a1ng 3 - B\u00e0i 12: Amino axit\" \/>\n<meta property=\"og:description\" content=\"B\u00e0i 1 (trang 66 sgk H\u00f3a 12 n\u00e2ng cao):\u00a0Ph\u00e1t bi\u1ec3u n\u00e0o sau \u0111\u00e2y \u0111\u00fang ? A. Trong ph\u00e2n t\u1eed amino axit ch\u1ec9 c\u00f3 m\u1ed9t nh\u00f3m \u2013NH2\u00a0v\u00e0 m\u1ed9t nh\u00f3m \u2013COOH B. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u kh\u00f4ng l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm C. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm D. 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A. Trong ph\u00e2n t\u1eed amino axit ch\u1ec9 c\u00f3 m\u1ed9t nh\u00f3m \u2013NH2\u00a0v\u00e0 m\u1ed9t nh\u00f3m \u2013COOH B. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u kh\u00f4ng l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm C. Dung d\u1ecbch c\u00e1c amino axit \u0111\u1ec1u l\u00e0m \u0111\u1ed5i m\u00e0u qu\u1ef3 t\u00edm D. 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